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Prediction of Rate Constants for Reactions of the Hydroxyl Radical in Water at High Temperatures and Pressures

✍ Scribed by Ghandi, Khashayar; Percival, Paul W.

Book ID
126418495
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
60 KB
Volume
107
Category
Article
ISSN
1089-5639

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πŸ“œ SIMILAR VOLUMES

The rate of methyl radical decomposition
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✍ J. Z. Su; H. Teitelbaum πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 605 KB

## Abstract Rate constants are calculated for CH~3~ (+ Ar) ⇄ CH~2~ + H (+ Ar) at the limiting low‐pressure, the limiting high‐pressure, as well as the intermediate fall‐off ranges. The results show that published experimental rate constants for methyl dissociation correspond to the fall‐off region

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Rate constants have been measured over the temperature range 245-419 K for the gas-phase reactions of the hydmxyl radical with the hydrofluorocarbons CHF,CF,CF,CHF, and CF&HFCHFCF2CF,. The Arrhenius expressions k (CHF,CF,CFzCHF,) =(7.80i3.40)X10-'3exp[-(1.51~0.26)~103/T] and k(CF,CHFCHFCF~CF,)=(4.21