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Prediction of excess enthalpies of ketone-alkane systems from infinite dilution activity coefficients

✍ Scribed by Shubao Shen; Isamu Nagata

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
529 KB
Volume
258
Category
Article
ISSN
0040-6031

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πŸ“œ SIMILAR VOLUMES

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Thermodynamically exact expressions for the activity coeflkient at infinite dilution have been developed. These involve the slopes of the total-pressure and boiling-point composition curves at the ends of the composition range. A graphical procedure is proposed for the more exact measurement of the

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Infinite-dilution activity coefficients of three (propanone + an \(n\)-alkane) mixtures were measured by a gas-stripping method in the \(298.15 \mathrm{~K}\) to \(318.15 \mathrm{~K}\) temperature region. The pre-saturation technique proposed by DoleΕΎal and co-workers was employed to make the measure