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Practical approach for catalytic asymmetric allylation of aldehydes with a chiral bidentate titanium(IV) complex

✍ Scribed by Satoshi Kii; Keiji Maruoka

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 111 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)00025-9

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✦ Synopsis

A new, chiral bidentate Ti(IV) complex of type 1 was successfully designed and can be utilized for simultaneous coordination to aldehyde carbonyls, thereby allowing the precise enantioface discrimination of such carbonyls for a new catalytic, practical enantioselective allylation of aldehydes with allyltributyltin.

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