Asymmetric Catalytic Alkylation of Aldehydes with Diethylzinc Using a Chiral Binaphthol-Titanium Complex
β Scribed by Maki Mori; Takeshi Nakai
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 527 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The asymmetric cotalytic cyanosilylationof oliphaticaldehydes with Me3SiCN using (R)-BINOL-Ti(O-i-Pr)2 m an arymmem"c precakdyst is shown to proceed smoothly in dichloromethane to ~ford the cyanohydrinsin rekdvely high enantiose!ectivity (up @ 75~oee). @1997 Elsevier ScienceLtd. Recently,much inter
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
A new, chiral bidentate Ti(IV) complex of type 1 was successfully designed and can be utilized for simultaneous coordination to aldehyde carbonyls, thereby allowing the precise enantioface discrimination of such carbonyls for a new catalytic, practical enantioselective allylation of aldehydes with a