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New Chiral Bis-Titanium(IV) Catalyst with Dibenzofuran Spacer for Catalytic Asymmetric Allylation of Aldehydes and Aryl Ketones

✍ Scribed by Hideo Hanawa; Satoshi Kii; Keiji Maruoka

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 89 KB
Volume: 343
Category: Article
ISSN: 1615-4150
DOI: 10.1002/1615-4169(20010129)343:1<57::aid-adsc57>3.0.co;2-o

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ChemInform Abstract: New Chiral Bis-tita

ChemInform Abstract: New Chiral Bis-titanium(IV) Catalyst with Dibenzofuran Spacer for Catalytic Asymmetric Allylation of Aldehydes and Aryl Ketones.

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ChemInform Abstract: Practical Approach

ChemInform Abstract: Practical Approach for Catalytic Asymmetric Allylation of Aldehydes with a Chiral Bidentate Titanium(IV) Complex.

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## Abstract Palladium‐catalyzed cross‐coupling of bipyridine __N,N′__‐dioxide 6,6′‐dichloride (__R__~__nap__~__,R__~__pyr__~)‐**1** with the aryl Grignard reagents opened a new approach to axially chiral bipyridine __N,N′‐__dioxides (__R__)‐**2** bearing a variety of aryl groups at the 6 and 6′ pos