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Potentials of zero charge, interaction of metals with water and adsorption of organic substances—I. Potentials of zero charge and hydrophilicity of metals

✍ Scribed by A. Frumkin; B. Damaskin; N. Grigoryev; I. Bagotskaya

Book ID
107748675
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
685 KB
Volume
19
Category
Article
ISSN
0013-4686

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Zero charge potential of metals
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## Zero charge potential of metals In place of the common reference hydrogen scale, electrode potentials can be advantageously referred to the potential of zero charge of the metal in question. The use of this rational scale of potentials is particularly valuable when the effect of the structure o

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Potentials of zero charge, interaction of metals with water and adsorption of organic substances—III. The role of the water dipoles in the structure of the dense part of the electric double layer
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Two types of solvent particles resident on the electrode surface have been considered: (1) associates of water molecules freely oriented aIong the electric field and (2) chemisorbed water dipoles oriented with the oxygen atom towards the metal surface. On the basis of this model, a semi-quantitative