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Potential surfaces for the unimolecular reactions of organic ions: C2H6N+ and C2H5O+

โœ Scribed by Bowen, Richard D.; Williams, Dudley H.; Hvistendahl, Georg

Book ID
125899601
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
885 KB
Volume
99
Category
Article
ISSN
0002-7863

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Potential energy profiles for unimolecul
Potential energy profiles for unimolecular reactions of organic ions: [C3H8N]+ and [C3H7O]+
โœ Richard D. Bowen; Dudley H. Williams; G. Hvistendahl; John R. Kalman ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 895 KB

The unimolecular decompositions of two isomers of [C&N]+, CH3CH2CH=NH2 and CH3CHzh=CH,, are dis-ed in terms of the potential energy profile over which reaction may be considered to occur. The energy needed to promote slow (metastable) dissociations of either ion is found to be less than that require