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Potential energy profiles for unimolecular reactions of isolated organic ions: some isomers of C4H10N+ and C5H12N+

โœ Scribed by Bowen, Richard D.


Book ID
120044346
Publisher
Royal Society of Chemistry
Year
1980
Tongue
English
Weight
919 KB
Volume
8
Category
Article
ISSN
1472-779X

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Potential energy profiles for unimolecul
โœ Richard D. Bowen; Dudley H. Williams; G. Hvistendahl; John R. Kalman ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 895 KB

The unimolecular decompositions of two isomers of [C&N]+, CH3CH2CH=NH2 and CH3CHzh=CH,, are dis-ed in terms of the potential energy profile over which reaction may be considered to occur. The energy needed to promote slow (metastable) dissociations of either ion is found to be less than that require