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Potential energy profiles for unimolecular reactions of organic ions: C4H9O+

โœ Scribed by Bowen, Richard D.; Williams, Dudley H.

Book ID
127330043
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
834 KB
Volume
100
Category
Article
ISSN
0002-7863

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Potential energy profiles for unimolecul
Potential energy profiles for unimolecular reactions of organic ions: [C3H8N]+ and [C3H7O]+
โœ Richard D. Bowen; Dudley H. Williams; G. Hvistendahl; John R. Kalman ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 895 KB

The unimolecular decompositions of two isomers of [C&N]+, CH3CH2CH=NH2 and CH3CHzh=CH,, are dis-ed in terms of the potential energy profile over which reaction may be considered to occur. The energy needed to promote slow (metastable) dissociations of either ion is found to be less than that require