Fully converged quantum cross sections for 4He-D2 (u= l,i=O) vibrational reliaxation were determined using the coupled-states method and a modikied version of the Gordon-Secrcst surface. First-order forbidden rotational transitions play a si@fkant role, comparable to that observed previously for the
Potential surface dependence of cross sections and rate constants for the vibrational relaxation of H2 in collisions with 4He
โ Scribed by Millard H. Alexander
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 986 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0301-0104
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๐ SIMILAR VOLUMES
A semiclassical collision modei has been irscd to cafcuhite the rate constant for vibrational reltxrtion in HD fu = 1, j = 0) colIid~ag with 4tie. The He + HD potential surface was obtained from an analyticat He + Hz surface previousfy used for similar c~caIatjons on NC f Hz and He + Dz\_ The fheorc
Cross secfiws and rate constants for the vibrat$onal Maxation of H&J = I,i= I) in collisions with 4He were determined using the coupled states method with a fulIy-converged channel basis. The interaction potential was taken to be that of Gordon and Secrest with the elastic matrix elements modified t
The vibrational relaxation of ortho-para-Hz in collisions with 4He has been studied in the interval 300-50 K. At 300 K the ortho Hz -He and para Hz-He rates are identical within experimental error. In the low temperature range ko~z\_~e