Potential constants and Coriolis coupling constants of perhalogenated ethylenes: Part 1. 1,1-Cl2C=CF2, 1,1-Cl2C=CBr2 and 1,1-F2C=CBr2
✍ Scribed by A. Reyes de Sánchez; J.R. Anacona; O. Noriega; J. Bermudez Castro
- Book ID
- 113258189
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 365 KB
- Volume
- 330
- Category
- Article
- ISSN
- 0166-1280
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## Abstract The competitive photochlorination and chlorine photosensitized dehydrochlorination of 1,1,1,2‐C~2~H~2~Cl~4~ have been studied over the temperature range of 349.4–404.5 K after less than 1% conversion. The results are discussed and a value of is proposed for the reaction This result,
Rate constants for the reactions of atomic oxygen ( 0 3 P ) with C&3F, C&IaCl,C@3Br, 1, l-CzHzFz, and I ,2-C&IzFz have been measured at 307' K using a discharge-flow system coupled to a mass spectrometer. The rate constants for these reactions are (in units of 1011cm3mole-1s-1)2.63 &0.38,5.22 =tO0.2