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Possible Evidence for a Two-Step Diels-Alder Reaction

✍ Scribed by Little, J. C.

Book ID
126129737
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
398 KB
Volume
87
Category
Article
ISSN
0002-7863

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Oxidation with barium manganate of the enol of dicyanobenzoquinone of meso-17 yields (E)-7b and an isomer (77:23) which was assigned structure (Z)-7b on the tetraacetylethane (10) affords tetraacetylethylene (7a) in good yield. Treatment of the 1,3-diketones 15a and b with basis of spectroscopic evi