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Porous solvent-free μ2-bis­(salicyl­idene)propane-1,3-diaminato-bis­{[bis­(salicyl­idene)propane-1,3-diaminato]iron(III)}

✍ Scribed by Bakir, Mohammed ;Dasgupta, Tara P. ;Dutta, Sujit K. ;Ngah, Nurziana ;Yamin, Bohari M.


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
344 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, [Fe 2 (C 17 H 16 N 2 O 2 ) 3 ], was isolated from the reaction between iron(III) perchlorate hydrate and a mixture of 1,3-bis(salicylideneamino)propane and triethylamine in ethanol. Recrystallization from a dichloroethane solution resulted in a porous solvent-free array of molecules. The molecule lies on a special position with twofold symmetry.


📜 SIMILAR VOLUMES


[N,N′-Bis(3-methyl­salicyl­idene)-1,3-pr
✍ You, Zhong-Lu 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 110 KB

The title compound, [Ni(C 19 H 20 N 2 O 2 )], is mononuclear. The Ni II atom is four-coordinated in a square-planar configuration by two N atoms and two O atoms of the Schiff base ligand. The molecule possesses crystallographic mirror symmetry.

[N,N′-Bis­(salicyl­idene)-1,3-propane­di
✍ You, Zhong-Lu ;Zhu, Hai-Liang ;Liu, Wei-Sheng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 459 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.036 wR factor = 0.107 Data-to-parameter ratio = 14.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

{[μ-Bis­(salicyl­idene)-1,3-propane­diam
✍ Ülkü, Dinçer ;Kaynak, F. Betül ;Atakol, Orhan 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 352 KB

The title compound, [NiZnBr 2 (C 17 H 16 N 2 O 2 )(C 7 H 9 N) 2 ], is a double oxygen-bridged heterometal complex based on a Schiff base ligand. The Ni atom has an irregular octahedral environment involving two bridging O and two N atoms from a SALPD 2À [N,N H -bis(salicylidene)-1,3-propanediaminate