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{[μ-Bis­(salicyl­idene)-1,3-propane­diaminato]bis(3,5-di­methyl­pyridine)nickel(II)}di­bromo­zinc(II)

✍ Scribed by Ülkü, Dinçer ;Kaynak, F. Betül ;Atakol, Orhan

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
352 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [NiZnBr 2 (C 17 H 16 N 2 O 2 )(C 7 H 9 N) 2 ], is a double oxygen-bridged heterometal complex based on a Schiff base ligand. The Ni atom has an irregular octahedral environment involving two bridging O and two N atoms from a SALPD 2À [N,N H -bis(salicylidene)-1,3-propanediaminate] ligand in the equatorial plane and two N atoms from two 3,5-dimethylpyridine molecules in the axial positions.

📜 SIMILAR VOLUMES

[N,N′-Bis(3-methyl­salicyl­idene)-1,3-pr
[N,N′-Bis(3-methyl­salicyl­idene)-1,3-propane­diaminato]nickel(II)
✍ You, Zhong-Lu 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 110 KB

The title compound, [Ni(C 19 H 20 N 2 O 2 )], is mononuclear. The Ni II atom is four-coordinated in a square-planar configuration by two N atoms and two O atoms of the Schiff base ligand. The molecule possesses crystallographic mirror symmetry.