Poly[[μ2-1,4-bis(3-pyridylmethoxy)benzene-hemi-μ2-fumarato-silver(I)] monohydrate]
✍ Scribed by Li, Shun-Li ;Bai, Hong-Ye ;Yang, Jin
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 628 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Ag(C~6~H~6~NO~3~S)(C~8~H~8~N~2~)], the Ag^I^ cation is four-coordinated by three N atoms from two different 2,3-diethylpyrazine ligands and one –NH~2~ group of a 4-aminobenzenesulfonate ligand, and one sulfonate O atom in a distorted tetrahedral coordination geometry. The Ag^
In the layer structure of the title polymeric complex, {[Ag 2 (C 7 H 5 O 6 S) 2 (H 2 O) 3 ]ÁH 2 O} n , both substituted benzenesulfonate anions use two of their sulfonyl O atoms to link to three Ag atoms and their double-bond carbonyl O atom to another Ag atom in a " 4 -bonding mode. The two symmetr