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Poly[[[pyrazino[2,3-f][1,10]phenanthroline]copper(II)]-μ4-fumarato-μ2-fumarato]

✍ Scribed by Che, Guang-Bo ;Liu, Chun-Bo ;Xu, Zhan-Lin

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
164 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the title compound, {[Cu(C~14~H~8~O~5~)(C~14~H~8~N~4~)]·H~2~O}~__n__~, the Cu^II^ atom adopts a distorted __cis__-CuN~2~O~2~ square-planar coordination geometry. 4,4′-Oxydibenzoate (__L__) ligands link the Cu^II^ atoms, generating a helical chain. Neighbouring chains are linked through π–π intera

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In the title polymeric complex, [Cd(C 4 H 2 O 4 )(C 12 H 8 N 2 )-(H 2 O) 2 ] n , the Cd II ions are bridged by fumarate dianions to form zigzag complex chains.stacking is observed between the parallel phenanthroline ligands of neighboring complex chains. The Cd ion is located on a twofold axis and h

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catena-Poly[[aqua(4,4 0 0 0 -dimethyl-2,2 0 0 0 -bipyridine)copper(II)]-l-fumarato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -[aqua-(4,4 0 0 0 -dimethyl-2,2 0 0 0 -bipyridine)copper(II)]l-fumarato-jO:jO 0 0 0 ]