Poly(ε-caprolactone) by combined ring-opening polymerization and azeotropic polycondensation—the role of cyclization and equilibration
✍ Scribed by Hans R. Kricheldorf; Steffen M. Weidner; Felix Scheliga
- Book ID
- 112175725
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 519 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0887-624X
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📜 SIMILAR VOLUMES
## Abstract **Summary:** The polymerization of __ε__‐caprolactone (CL) in the presence of HCl · Et~2~O by an activated monomer mechanism was performed to synthesize diblock or triblock copolymers composed of poly(ethylene glycol) (PEG) and poly(__ε__‐caprolactone) (PCL). The obtained PCLs had molec
## Abstract PCL/clay nanocomposites were prepared by microwave‐assisted in situ ROP of __ε__‐caprolactone in the presence of either unmodified clay (Cloisite® Na^+^) or clay modified by quaternary ammonium cations containing hydroxyl groups (Cloisite 30B). This PCL showed significantly improved mon