Ring-Opening Polymerization of α-Chloro-ε-caprolactone and Chemical Modification of Poly(α-chloro-ε-caprolactone) by Atom Transfer Radical Processes
✍ Scribed by Lenoir, S.; Riva, R.; Lou, X.; Detrembleur, Ch.; Jérôme, R.; Lecomte, Ph.
- Book ID
- 120171545
- Publisher
- American Chemical Society
- Year
- 2004
- Tongue
- English
- Weight
- 138 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0024-9297
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📜 SIMILAR VOLUMES
Poly(-caprolactone) (PCL) macromonomers capped by a polymerizable norbornene end-group have been synthesized and (co)polymerized by ring-opening metathesis with formation of graft copolymers and polymacromonomers. ␣-Norbornenyl PCL macromonomers have been synthesized by ring opening polymerization (
## Abstract **Summary:** A series of PCL‐__b__‐PVPh diblock copolymers were prepared through combinations of ring‐opening and atom‐transfer radical polymerizations of __ε__‐caprolactone and 4‐acetoxystyrene, and subsequent selective hydrolysis of the acetyl protective group. This PCL‐__b__‐PVPh dib
## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym