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Poly[propane-1,3-diammonium hydroxy­deca-μ2-oxo-penta­borate]

✍ Scribed by Wang, Guo-Ming ;Pan, Chun-Yang ;Zheng, Shou-Tian ;Yang, Guo-Yu


Book ID
104489735
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
209 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


The title compound, {C~3~H~12~N~2~
^2+^·B~5~O~8~(OH)^2−^}~n~, has been synthesized under mild solvothermal conditions in the presence of 1,3-diaminopropane acting as a template. The structure consists of two-dimensional polymeric sheets constructed from [B~5~O~8~(OH)]^2−^ pentaborate anions. Adjacent borate sheets are linked by O—H...O hydrogen bonds to form a three-dimensional framework with channels running along one direction. The propane-1,3-diammonium cations lie within the channels, interacting with the framework through N—H...O hydrogen bonds.


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