The title compound, {C~2~H~10~N~2~ ^2+^·B~5~O~8~(OH)^2−^}~__n__~, has been hydrothermally synthesized. The structure consists of two-dimensional polymeric sheets constructed from [B~5~O~8~(OH)]^2−^ pentaborate anions. Adjacent borate sheets are linked by O—H...O hydrogen bonds into a three-dimension
Poly[propane-1,3-diammonium hydroxydeca-μ2-oxo-pentaborate]
✍ Scribed by Wang, Guo-Ming ;Pan, Chun-Yang ;Zheng, Shou-Tian ;Yang, Guo-Yu
- Book ID
- 104489735
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 209 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, {C~3~H~12~N~2~
^2+^·B~5~O~8~(OH)^2−^}~n~, has been synthesized under mild solvothermal conditions in the presence of 1,3-diaminopropane acting as a template. The structure consists of two-dimensional polymeric sheets constructed from [B~5~O~8~(OH)]^2−^ pentaborate anions. Adjacent borate sheets are linked by O—H...O hydrogen bonds to form a three-dimensional framework with channels running along one direction. The propane-1,3-diammonium cations lie within the channels, interacting with the framework through N—H...O hydrogen bonds.
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The title polymeric compound, {(C~3~H~12~N~2~)[Co(C~10~H~2~O~8~)(H~2~O)~2~]·0.5H~2~O}~__n__~, was obtained by the reaction of cobalt(II) nitrate hexahydrate with the proton-transfer compound (pnH~2~)~2~(btc)·2H~2~O (pn = propane-1,3-diamine and btcH~4~ = benzene-1,2,4,5-tetracarboxylic acid) in aque
The title compound, {[Ag(C 15 H 16 S 2 ) 2 ]SbF 6 Á0.5C 4 H 10 O} n , was obtained from the self-assembly of AgSbF 6 and 1,3-bis-(phenylsulfanyl)propane. Each Ag I ion is coordinated by four S atoms from different ligands, forming a distorted tethrahedral geometry. Each ligand links adjacent Ag I io