Polymerizations with contribution of covalent and ionic species
โ Scribed by Penczek, Stanislaw; Szymanski, Ryszard; Duda, Andrzej
- Book ID
- 120353054
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 937 KB
- Volume
- 98
- Category
- Article
- ISSN
- 1022-1360
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๐ SIMILAR VOLUMES
Structure and reactivities in the cationic polymerization of the heterocyclic monomers is reviewed. Particularly the equilibria between major kinds of active species, including the kinetics of interconversions between the covalent species and the corresponding macroion-pairs are discussed. Reason fo
## Abstract The problem of computing of the covalent and ionic species contribution to the chain building in propagation is discussed, and it is shown that under certain conditions the reversibility of propagation does not influence the contribution of the given species.
## Abstract Contributions of the covalent and ionic species to the chain building in cationic reversible polymerizations are analyzed by means of Monte Carlo simulations and by solving the formulated set of equations. The validity of the equation for the contribution of covalent propagation, derive