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Covalent and ionic species in cationic polymerizations: Rates of exchange

✍ Scribed by Penczek, Stanislaw; Szymanski, Ryszard


Book ID
120353052
Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
391 KB
Volume
13-14
Category
Article
ISSN
1022-1360

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Structure and reactivities in the cationic polymerization of the heterocyclic monomers is reviewed. Particularly the equilibria between major kinds of active species, including the kinetics of interconversions between the covalent species and the corresponding macroion-pairs are discussed. Reason fo

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## Abstract The ionization of 1‐chloro‐1‐isobutoxyethane (IBVCI) in the presence of BCI~3~ in CD~2~Cl~2~ and CD~2~Cl~2~/CDCl~3~ mixtures at variable temperatures was studied by ^1^H NMR spectroscopy. The presence of only one NMR signal for the methine proton in the intermediate stage of ionization