In this work, a seeded soapless emulsion polymerization was carried out with crosslinking (XL) poly(methyl methacrylate) (PMMA) as seeds, styrene as monomer, and potassium persulfate (K 2 S 2 O 8 ) as initiator to synthesize the PMMA XL-PS composite latex, which we knew as the latex interpenetrating
Polymerization studies on allylic compounds. III. α(substituted methyl)styrenes
✍ Scribed by Baldwin, M. G. ;Reed, Samuel F.
- Book ID
- 104534573
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1968
- Tongue
- English
- Weight
- 480 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0449-296X
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The AM1 results of the relative reactivity and the angle of deviation from the coplanarity between developing carbenium ion and the benzene n-system in the TS for SN~ reactions of a-t-butylbenzyl systems agree well with those of the expahentally observed.
## Abstract α‐Alkylation of the α,β‐unsaturated ketone 1 at C‐4 has been achieved by thioalkylation of the corresponding zinc dienolate with α‐chlorosulfides of type 2. The desulfurization of the β‐(phenylthio) ketones 4 leads directly to the 4‐substituted hexahydroinden‐5‐ones 5. magnified image