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Theoretical studies of the effects of ortho methyl substitution on the SN1 reactions of α-t-butylbenzyl compounds

✍ Scribed by Lee Ikchoon; Doo Kim Nam; Kon Kim Chang

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
253 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis

The AM1 results of the relative reactivity and the angle of deviation from the coplanarity between developing carbenium ion and the benzene n-system in the TS for SN~ reactions of a-t-butylbenzyl systems agree well with those of the expahentally observed.

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