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Polymerization of styrene initiated by heterogeneous macromolecular initiator

✍ Scribed by D. Mikulášová; V. Chrástová; P. Citovický


Book ID
107753362
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
404 KB
Volume
10
Category
Article
ISSN
0014-3057

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Cationic polymerization of styrene initi
✍ Takumi Taninaka; Yuji Minoura 📂 Article 📅 1977 🏛 Elsevier Science 🌐 English ⚖ 378 KB

Cationic polymerization of styrene(St) initiated by phosphorus trichloride(PC13) in nitrobenzene was carried out at 30 °. The initial rate was proportional to [St] 2 and [PCl3]. The overall activation energy was about 10.4 kcal/mole. The rate and the degree of polymerization were enhanced with incre