Radical polymerization of styrene initiated by styrene–arsenic sulfide complex
✍ Scribed by Prerna Shukla; A. K. Srivastava
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 216 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0887-624X
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## Abstract We demonstrated that density functional theory calculations provide a prediction of the trends in C‐S bond dissociation energies and atomic spin densities for radicals using two model compounds as diethyldithiocarbamate (DC)‐mediated iniferters. On the basis of this information, we synt
Segmented poly(ethylene oxide) macroinitiators containing bistrialkylbenzopinacolate groups were used to initiate radical polymerization of styrene. A polystyrene-PEO block copolymer is formed by the incorporation of the PEO macroinitiator. The PEO fraction in the copolymer decreases with increasing