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Polymerization of Methylene Dichloride and Sodium Tetrasulfide: Synthesis and Kinetic Studies

โœ Scribed by Kalaee, M. R.; Famili, M. H. N.; Dadgar, M.; Olyai, M. R. Talei Bavil; Naderi, A.


Book ID
126755279
Publisher
Taylor and Francis Group
Year
2010
Tongue
English
Weight
266 KB
Volume
185
Category
Article
ISSN
1042-6507

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Kinetic and ESR studies on radical polym
โœ T. Sato; Y. Hirose; M. Seno; H. Tanaka; N. Uchiumi; M. Matsumoto ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 391 KB

The polymerization of diisopropyl itaconate (DIPI) initiated with dimethyl 2,2'-azobisisobutyrate(MAIB) was investigated kinetically in benzene. The polymerization rate (Rp) was expressed by R v = k[MAIB]ยฐ46[I)IPI] 16 at 50 ยฐ. The overall activation energy of the polymerization was calculated to be