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Polymerization of methyl methacrylate by alkali metal compounds

✍ Scribed by Lím, D. ;Čoupek, J. ;Jůzl, K. ;Báča, J. ;Sýkora, S. ;Schneider, B.


Book ID
105340393
Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
367 KB
Volume
23
Category
Article
ISSN
0449-2994

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Polymerization of methyl methacrylate by
✍ P.E.M. Allen; B.A. Casey 📂 Article 📅 1966 🏛 Elsevier Science 🌐 English ⚖ 294 KB

The polymerizations of methyl methacrylate and methyl acrylate in the presence of triethylaluminlum are photochemical. The initiator is a yellow complex formed between monomer and triethyl-aluminium. Experimental evidence is weighted against a radical mechanism. An anionic insertion mechanism involv