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Polymerization of methyl methacrylate by organo-metallic compounds. The mechanism of initiation by triethyl-aluminium

✍ Scribed by P.E.M. Allen; B.A. Casey

Publisher: Elsevier Science
Year: 1966
Tongue: English
Weight: 294 KB
Volume: 2
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(66)90055-3

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✦ Synopsis

The polymerizations of methyl methacrylate and methyl acrylate in the presence of triethylaluminlum are photochemical. The initiator is a yellow complex formed between monomer and triethyl-aluminium. Experimental evidence is weighted against a radical mechanism. An anionic insertion mechanism involving the photo-excited state of the yellow complex is proposed.

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