Methyl methacrylate was polymerized with Cp 2 YCl(THF) or IVB group metallocene compounds (i.e., Cp 2 ZrCl 2 and Cp 2 HfCl 2 , etc.), in the presence of a Lewis acid like Zn(C 2 H 5 ) 2 . The Lewis acid was complexed with methyl methacrylate, which avoided the metallocene compounds being poisoned wi
โฆ LIBER โฆ
Polymerization of methyl methacrylate by metallocenes
โ Scribed by Kyoji Kaeriyama
- Publisher
- Elsevier Science
- Year
- 1971
- Tongue
- English
- Weight
- 420 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0032-3861
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## Abstract Methyl methacrylate (MMA) was polymerized with Cp~2~ZrCl~2~/ methylalyminoxane or Cp~2~M(CH~3)~~2~ (M: Zr, Hf; Cp = cyclopentadienyl) combined with B(C~6~F~5~)~3~ (1) or Ph~3~CB(C~6~F~5~)~4~ (2), (Ph = phenyl). in the presence of a Lewis acid like Zn(C~2~H~5~)~2~ with slow inititation,
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