## Abstract Methyl methacrylate (MMA) was polymerized by thiophenol without oxidants. Hydroquinone had no effect on the polymerization, indicating that the polymerization proceeded via a nonβradical process. Since other monomers with an __x__,Ξ²βunsaturated carbonyl group polymerized similarly, the
β¦ LIBER β¦
Polymerization of methyl methacrylate initiated by arylcarbene
β Scribed by Imoto, Minoru ;Nakaya, Tadao ;Tomomoto, Takanori ;Ohasi, Koichi
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1966
- Tongue
- English
- Weight
- 120 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0449-2986
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## Abstract The freeβradical polymerization of methyl methacrylate at low temperatures has been studied in a series of solvents of differing solvent power and ability to form weak complexes with monomer. In every case the polymer was predominantly syndiotactic, which suggests that monomer associati