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Polymerization of Lactides and Lactones by Metal-Free Initiators †

✍ Scribed by Li, Hong; Wu, Jun; Brunel, Sylvain; Monnet, Christiane; Baudry, Roselyne; Le Perchec, Pierre

Book ID
126236656
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
62 KB
Volume
44
Category
Article
ISSN
0888-5885

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Polyether dendrons have been successfully used as macroinitiators for the living ring-opening polymerization (ROP) of lactones and lactides. A hydroxyl group located at the focal point of dendrimers of different generations was transformed into diethyl aluminum alkoxides by reaction with triethyl al