Ring-Opening Polymerization of Lactones and Lactides with Sn(IV) and Al(III) Initiators
โ Scribed by von Schenck, Henrik; Ryner, Maria; Albertsson, Ann-Christine; Svensson, Mats
- Book ID
- 118268060
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 183 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0024-9297
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๐ SIMILAR VOLUMES
Ring-opening polymerization of -caprolactone (CL) has been initiated with rare earth phenyl compounds in both bulk and solution. These rare earth phenyl initiators can give polycaprolactone (PCL) with high yield and high molecular weight. The polymerization mechanism is through a coordination-deprot
Polyether dendrons have been successfully used as macroinitiators for the living ring-opening polymerization (ROP) of lactones and lactides. A hydroxyl group located at the focal point of dendrimers of different generations was transformed into diethyl aluminum alkoxides by reaction with triethyl al