Aluminium alkoxides: A family of versatile initiators for the ring-opening polymerization of lactones and lactides
✍ Scribed by Dubois, Ph.; Jérǒme, R.; Teyssié, Ph.
- Book ID
- 121262177
- Publisher
- John Wiley and Sons
- Year
- 1991
- Tongue
- English
- Weight
- 481 KB
- Volume
- 42-43
- Category
- Article
- ISSN
- 1022-1360
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📜 SIMILAR VOLUMES
Polyether dendrons have been successfully used as macroinitiators for the living ring-opening polymerization (ROP) of lactones and lactides. A hydroxyl group located at the focal point of dendrimers of different generations was transformed into diethyl aluminum alkoxides by reaction with triethyl al
Successful room temperature ring-opening polymerization (ROP) of e-caprolactone and d-valerolactone has been carried out using SmX 2 (X = I, Br, and cyclopentadienyl (Cp)) catalysts. SmI 2 in the presence of metallic Sm was found to have enhanced reactivity as room temperature ROP initiator for lact