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Polymerization of DL-β-PhenyIalanine N-Carboxyanhydride by Poly(N-n-propylglycine) Diethylamide

✍ Scribed by Sisido, Masahiko; Imanishi, Yukio; Okamura, Seizo


Book ID
121800359
Publisher
Nature Publishing Group
Year
1970
Tongue
English
Weight
790 KB
Volume
1
Category
Article
ISSN
0032-3896

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📜 SIMILAR VOLUMES


Polymerization of optical isomers of phe
✍ Yukio Imanishi; Kazuya Kugimiya; Toshinobu Higashimura 📂 Article 📅 1974 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 400 KB

## Abstract In the polymerization of phenylalanine __N__‐carboxyanhydride (NCA) using poly(__N__‐methyl‐L‐or DL‐alanine) diethylamide as initiator, the polymerization rate was L‐NCA ≃ D‐NCA > DL‐NCA. This is a new type of selective polymerization and indicates the incompleteness of earlier investig

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✍ Masahiko Sisido; Yukio Imanishi; Seizo Okamura 📂 Article 📅 1970 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 410 KB

## Abstract The polymerization of DL‐β‐phenylalanine __N__‐carboxyanhydride (NCA) initiated by poly(__N__‐benzylglycine)diethylamide (DEA) and poly(__N__‐methyl‐DL‐alanine)DEA has been investigated. As previously reported, polysarcosine DEA, poly‐__N__‐ethylglycine DEA, and poly‐__N__‐__n__‐propylg

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✍ Yukio Imanishi; Kazuya Kugimiya; Toshinobu Higashimura 📂 Article 📅 1973 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 617 KB

## Abstract Polymerizations of L‐ and DL‐phenylalanine __N__‐carboxyanhydride in nitrobenzene by poly (__N__‐methyl‐L‐alanine) of varying degrees of polymerization (__n__ = 1–30) were investigated. Poly(__N__‐methyl‐L‐alanine) was prepared by the polymerization of __N__‐methyl‐L‐alanine NCA with __

Synthesis and polymerization of N-carbox
✍ Albert Zilkha; Yigal Burstein 📂 Article 📅 1964 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 801 KB

The NCAs of the N-benzyl derivatives of 8-alanine, j3-nL-aminobutyric acid, and j3nkaminoisobutyric acid (nonplanar six-membered rings) were prepared by reacting the corresponding N-chloroformyl derivatives, obtained on reaction of the N-benzyl amino acids with phosgene, with triethylamine. Contrary