## Abstract Polymerizations of L‐ and DL‐phenylalanine __N__‐carboxyanhydride in nitrobenzene by poly (__N__‐methyl‐L‐alanine) of varying degrees of polymerization (__n__ = 1–30) were investigated. Poly(__N__‐methyl‐L‐alanine) was prepared by the polymerization of __N__‐methyl‐L‐alanine NCA with __
Polymerization of DL-Phenylalanine N-Carboxyanhydride by Multifunctional Pyridine Derivatives
✍ Scribed by Imanishi, Yukio; Nagaoka, Shoji; Higashimura, Toshinobu
- Book ID
- 121800360
- Publisher
- Nature Publishing Group
- Year
- 1973
- Tongue
- English
- Weight
- 745 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0032-3896
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📜 SIMILAR VOLUMES
## Abstract The polymerization of DL‐β‐phenylalanine __N__‐carboxyanhydride (NCA) initiated by poly(__N__‐benzylglycine)diethylamide (DEA) and poly(__N__‐methyl‐DL‐alanine)DEA has been investigated. As previously reported, polysarcosine DEA, poly‐__N__‐ethylglycine DEA, and poly‐__N__‐__n__‐propylg
## Abstract In the polymerization of phenylalanine __N__‐carboxyanhydride (NCA) using poly(__N__‐methyl‐L‐or DL‐alanine) diethylamide as initiator, the polymerization rate was L‐NCA ≃ D‐NCA > DL‐NCA. This is a new type of selective polymerization and indicates the incompleteness of earlier investig
## Abstract In the polymerization of phenylalanine NCA initiated by some secondary amines, the two enatimorphs of phenylalanine NCA were polymerized with the same rate, which was almost twice as high, as that found for the racemic mixture. This stereoselectivity was observed only when the polymeriz