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Polymerization of acrylonitrile catalyzed by thiolate complexes of divalent and trivalent lanthanoids

✍ Scribed by Nakayama, Yuushou; Fukumoto, Hiroki; Shibahara, Tetsuya; Nakamura, Akira; Mashima, Kazushi

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 57 KB
Volume: 48
Category: Article
ISSN: 0959-8103
DOI: 10.1002/(sici)1097-0126(199906)48:6<502::aid-pi180>3.0.co;2-b

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✦ Synopsis

Arenethiolate complexes of lanthanoid(II) and lanthanoid(III) metals were used as initiators for the polymerization of acrylonitrile at À78 °C in THF, giving atactic and high molecular mass (M n % 10 5 ) polyacrylonitriles in good yield.

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