Titanium and zirconium complexes with a pyridine diamide ligand, [2,6-(RNCH 2 ) 2 NC 5 H 3 ] 2Ϫ (PDMP; R ϭ 2,6-dimethylphenyl) have been synthesized and their catalytic behaviors investigated for ethylene polymerization. It was found that the zirconium complexes, [PDMP]ZrCl 2 (7) and [PDMP][ZrCl 3 ϫ
✦ LIBER ✦
Ethylene polymerization catalyzed by diamide complexes of Ti(IV) and Zr(IV)
✍ Scribed by Carlos L. P. Carone; Fabiana C. Fim; Rubens Bisatto; Vanusca D. Jahno; Cristóvão Lemos; Nara R. S. Basso; Sandra Einloft; Griselda Barrera Galland
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 101 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0021-8995
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