𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Highly Enantioselective Cyanosilylation of Ketones Catalyzed by a Bifunctional Ti(IV) Complex.

✍ Scribed by Ke Shen; Xiaohua Liu; Qinghan Li; Xiaoming Feng

Publisher
John Wiley and Sons
Year
2008
Weight
47 KB
Volume
39
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Enantioselective Cyanosilylation of Keto
Enantioselective Cyanosilylation of Ketones Catalyzed by a Nitrogen-Containing Bifunctional Catalyst
✍ Yan Xiong; Xiao Huang; Shaohua Gou; Jinglun Huang; Yuehong Wen; Xiaoming Feng πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 138 KB πŸ‘ 2 views

## Abstract An efficient and optically active, bifunctional tetraaza ligand (2__S__)‐__N__‐{(1__R__,2__R__)‐2‐[(__S__)‐pyrrolidine‐2‐carboxamido]‐1,2‐diphenylethyl}pyrrolidine‐2‐carboxamide has been developed for the addition of trimethylsilyl cyanide (TMSCN) to ketones. The bifunctional catalyst s

ChemInform Abstract: A Novel Bifunctiona
ChemInform Abstract: A Novel Bifunctional Ti(IV) Complex Catalyzed Asymmetric Silylcyanation of Aldehydes.
✍ Hongying Tang; Zhongbiao Zhang πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 33 KB

## Abstract A novel Lewis acid and Lewis base bifunctional Ti(IV) complex is formed in situ by treatment of synthesized BINOL ligand with isopropyl titanate(IV), which is an efficient catalyst in the asymmetric trimethylsilylcyanation of aldehydes.