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ChemInform Abstract: A Novel Bifunctional Ti(IV) Complex Catalyzed Asymmetric Silylcyanation of Aldehydes.

✍ Scribed by Hongying Tang; Zhongbiao Zhang

Publisher: John Wiley and Sons
Year: 2011
Weight: 33 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201118072

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✦ Synopsis

Abstract

A novel Lewis acid and Lewis base bifunctional Ti(IV) complex is formed in situ by treatment of synthesized BINOL ligand with isopropyl titanate(IV), which is an efficient catalyst in the asymmetric trimethylsilylcyanation of aldehydes.

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