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ChemInform Abstract: Asymmetric Hydrophosphonylation of Aldehydes Catalyzed by Bifunctional Chiral Al(III) Complexes.

✍ Scribed by Shaohua Gou; Xin Zhou; Jun Wang; Xiaohua Liu; Xiaoming Feng

Publisher
John Wiley and Sons
Year
2008
Weight
40 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract The asymmetric alkynylation of aldehydes catalyzed by bifunctional Zn(salen) catalyst was realized. With a Kozlowski salen ligand (7e) bearing secondary basic 1‐piperidinylmethyl groups at C‐3 and C‐3β€², the enhanced catalytic reactivity and stereoselectivity in comparison with that of n