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ChemInform Abstract: Head-to-Head Z Dimerization of Terminal Alkynes Catalyzed by Thiolate-Bridged Diruthenium Complexes.

โœ Scribed by Jing-Ping Que; Dai Masui; Youichi Ishii; Masanobu Hidai


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Ruthenium-Catalyzed
โœ C. SLUGOVC; K. MEREITER; E. ZOBETZ; R. SCHMID; K. KIRCHNER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB

Ruthenium-Catalyzed Dimerization of Terminal Alkynes Initiated by a Neutral Vinylidene Complex. -The catalytic coupling of alkynes (III) or (VI) in the presence of Ru complexes such as (I) or (II) leads to butenynes with both conversion and selectivity strongly depending on the alkyne substituent.