Polymerization of 1-hexene, 1-octene catalyzed by Cp′TiCl2(O-2,6-iPr2C6H3)–MAO system. Unexpected increase of the catalytic activity for ethylene/1-hexene copolymerization by (1,3-tBu2C5H3)TiCl2(O-2,6-iPr2C6H3)–MAO catalyst system

✍ Scribed by Kotohiro Nomura; Takashi Komatsu; Yukio Imanishi

• Publisher: Elsevier Science
• Year: 2000
• Tongue: English
• Weight: 69 KB
• Volume: 152
• Category: Article
• ISSN: 1381-1169
• DOI: 10.1016/s1381-1169(99)00388-x

✦ Synopsis

Ž

. methylaluminoxane MAO catalysts, 4 exhibited the significant catalytic activity for copolymerization of ethylene with Ž . 1-hexene, resulting in obtaining a copolymer with relatively high 1-hexene content 20.2-36.5 mol% with relatively narrow molecular weight distribution.