## Ž . methylaluminoxane MAO catalysts, 4 exhibited the significant catalytic activity for copolymerization of ethylene with Ž . 1-hexene, resulting in obtaining a copolymer with relatively high 1-hexene content 20.2-36.5 mol% with relatively narrow molecular weight distribution.
✦ LIBER ✦
Effect of cocatalyst in 1-hexene polymerization by Cp∗TiMe2(O-2,6-iPr2C6H3) complex
✍ Scribed by Kotohiro Nomura; Takashi Komatsu; Miho Nakamura; Yukio Imanishi
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 88 KB
- Volume
- 164
- Category
- Article
- ISSN
- 1381-1169
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Polymerization of propylene was conducted at 0 -150°C with the [ArN(CH2)3NAr]TiClz (Ar = 2,6-'Pr2C6H3) complex using a mixture of ~a l k y l a l u m i n i ~ (AIR3, R = methyl, ethyl and isobutyl) and Ph3CB(C&& as cocatalyst. When AlMe3 or AlEt3 was employed, atactic polypropylene (PP) was selectivel