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Ligand effect in olefin polymerization catalyzed by (cyclopentadienyl)(aryloxy) titanium(IV) complexes, Cp′TiCl2(OAr)–MAO system.: Ethylene/1-hexene copolymerization by (1,3-tBu2C5H3)TiCl2(O-2,6-iPr2C6H3)–MAO catalyst system

✍ Scribed by Kotohiro Nomura; Takashi Komatsu; Yukio Imanishi

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
140 KB
Volume
159
Category
Article
ISSN
1381-1169

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Polymerization of 1-hexene, 1-octene catalyzed by Cp′TiCl2(O-2,6-iPr2C6H3)–MAO system. Unexpected increase of the catalytic activity for ethylene/1-hexene copolymerization by (1,3-tBu2C5H3)TiCl2(O-2,6-iPr2C6H3)–MAO catalyst system
✍ Kotohiro Nomura; Takashi Komatsu; Yukio Imanishi 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 69 KB

## Ž . methylaluminoxane MAO catalysts, 4 exhibited the significant catalytic activity for copolymerization of ethylene with Ž . 1-hexene, resulting in obtaining a copolymer with relatively high 1-hexene content 20.2-36.5 mol% with relatively narrow molecular weight distribution.