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Polymerization and conformation of N-carboxy anhydrides of a L-glutamic acid derivative in monolayer

โœ Scribed by Shibata, Akira.; Hashimura, Yuko.; Yamashita, Shinsuke.; Ueno, Satoru.; Yamashita, Takuya.


Book ID
126436898
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
524 KB
Volume
7
Category
Article
ISSN
0743-7463

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โœ Etsco Hasegawa; Toshiaki Shibata; Haruyuki Takeuchi; Eishun Tsuchida ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 317 KB

The polymerization of 7-benzyl-L-glutamate N-carboxy anhydride initiated by ~,~-primary diamines was studied kinetically in N,N-dimethylformamide by measuring the amounts of carbon dioxide evolved during polymerization and compared with those initiated by ~-primary monoamines. The pseudo first-order