Polymerization and conformation of N-carboxy anhydride of .gamma.-dodecyl L-glutamate in monolayer
β Scribed by Shibata, Akira; Oasa, Akiko; Hashimura, Yuko; Yamashita, Shinsuke; Ueno, Satoru; Yamashita, Takuya
- Book ID
- 126834077
- Publisher
- American Chemical Society
- Year
- 1990
- Tongue
- English
- Weight
- 583 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0743-7463
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π SIMILAR VOLUMES
The polymerization of 7-benzyl-L-glutamate N-carboxy anhydride initiated by ~,~-primary diamines was studied kinetically in N,N-dimethylformamide by measuring the amounts of carbon dioxide evolved during polymerization and compared with those initiated by ~-primary monoamines. The pseudo first-order
Poly--pbenzyl-cglutamate prepared by polymerization of 7-benzyl-Lglutamate NCA in dimethylformamide (DMF) with the use of diisopropylamine as the initiator was precipitated from the polymerization mixture under different conditions. A portion of the almost completely polymerized solution was treated