The polymerization of 7-benzyl-L-glutamate N-carboxy anhydride initiated by ~,~-primary diamines was studied kinetically in N,N-dimethylformamide by measuring the amounts of carbon dioxide evolved during polymerization and compared with those initiated by ~-primary monoamines. The pseudo first-order
Surface-initiated ring opening polymerization of N-carboxy anhydride of benzyl-l-glutamate monomers on soft flexible substrates
✍ Scribed by Duran, Hatice; Yameen, Basit; Khan, Hadayat Ullah; Förch, Renate; Knoll, Wolfgang
- Book ID
- 121445770
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 1008 KB
- Volume
- 73
- Category
- Article
- ISSN
- 1381-5148
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Poly--pbenzyl-cglutamate prepared by polymerization of 7-benzyl-Lglutamate NCA in dimethylformamide (DMF) with the use of diisopropylamine as the initiator was precipitated from the polymerization mixture under different conditions. A portion of the almost completely polymerized solution was treated