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Polymere charge-transfer-Komplexe auf der basis von polyvinylalkoholacetalen, 3

✍ Scribed by Geißler, Ulrich ;Schulz, Rolf C.

Book ID
102481018
Publisher
Wiley (John Wiley & Sons)
Year
1980
Weight
371 KB
Volume
181
Category
Article
ISSN
0025-116X

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✦ Synopsis

Abstract

A new fluorene containing polymer, poly[2‐(2‐fluorenyl)‐1,3‐dioxan‐4,6‐diylmethylene] (3 or 4), and the corresponding model compound, 2‐fluorenecarbaldehydetrimethyleneacetal (6) were synthesized. The fluorescence spectroscopy of the polymer in dilute solution indicates the formation of an intramolecular excimer. Charge‐transfer complex formation with tetracyanoethylene (TCNE), 2,5‐cyclohexadien‐1,4‐diylidenedimalonodinitrile (TCNQ), and 2,4,5,7‐tetranitro‐9‐fluorenone (TENF) was studied by means of absorption spectroscopy.

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