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Polymere hydrochinoncarbonamide. Darstellung von redoxharzen auf der basis von N-(3-vinylphenyl)-2,5-dihydroxy-4-methylbenzamid bzw. N-(2,5-dihydroxy-4-methylphenyl)-4-vinylbenzamid

✍ Scribed by Manecke, Georg ;Krämer, Andreas ;Wehr, Gregor

Book ID
102481731
Publisher
Wiley (John Wiley & Sons)
Year
1978
Weight
402 KB
Volume
179
Category
Article
ISSN
0025-116X

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✦ Synopsis

Abstract

N‐(3‐Vinylphenyl)‐2,5‐dimethoxy‐4‐methylbenzamide (3) was synthesized. By copolymerization of 3 and of N‐(2,5‐dimethoxy‐4‐methylphenyl)‐4‐vinylbenzamide, respectively, with 4‐vinylpyridine and 1,4‐divinylbenzene protected redox resins were obtained. By removal of the protective groups the corresponding free redox resins were obtained. Their chemical stability and redox capacities were investigated. The influence of the anilinocarbonyl group on the midpoint potential of the hydroquinone/quinone system was studied on the model compound N‐phenyl‐2,5‐dihydroxy‐4‐methylbenzamide.

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Polymere N-Acylaminohydrochinone. Darste
Polymere N-Acylaminohydrochinone. Darstellung von polymerem N-(2,5-dihydroxy-4-methyl)phenyl-p-vinylbenzamid und einiger modellverbindungen
✍ Wehr, Gregor ;Duchstein, Hans-Jürgen ;Manecke, Georg 📂 Article 📅 1974 🏛 Wiley (John Wiley & Sons) ⚖ 665 KB

## Abstract Einige vinylgruppenhaltige __N__‐Acylaminohydrochinone wurden dargestellt. __N__‐(2,5‐Dimethoxy‐4‐methyl)phenyl‐__p__‐vinylbenzamid (**2**) konnte radikalisch polymerisiert werden. Die Entmethylierung des polymeren Hydrochinondimethyläthers (**3**) führte zum Redoxpolymeren, in dem die