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Polyhedral oligomeric silsesquioxane-bound iminofullerene

✍ Scribed by David J. Clarke; Janis G. Matisons; George P. Simon; Marek Samoc; Anna Samoc

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
381 KB
Volume
24
Category
Article
ISSN
0268-2605

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✦ Synopsis

Abstract

Polyhedral oligomeric silsesquioxane (POSS) cages containing an iminofullerene species are reported herein. Monosubstituted benzyl chloride POSS was synthesized, and subsequently reacted with sodium azide to form mono benzyl azide POSS. The azide was subsequently reacted with C~60~ in anhydrous, degassed toluene to yield the desired POSS iminofullerene compound. The prepared compounds were characterized by multinuclear NMR, electrospray mass spectrometry, elemental analysis, UV–vis, fluorescence and optical power limiting measurements. Copyright © 2009 John Wiley & Sons, Ltd.

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